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Several other separation methods that can also be considered equilibrium stage processes will be briefly discussed.
Chapters 17 and 18 explore two important separations—membrane separators and adsorption processes—that do not operate as equilibrium stage systems.
The equilibrium stage concept is applicable when the process can be constructed as a series of discrete stages in which the two phases are contacted and then separated.
The two separated phases are assumed to be in equilibrium with each other. For example, in distillation, a vapor and a liquid are commonly contacted on a metal plate with holes in it.
Because of the intimate contact between the two phases, solute can transfer from one phase to another.
Above the plate the vapor disengages from the liquid. Both liquid and vapor can be sent to additional stages for further separation. Assuming that the stages are equilibrium stages, the engineer can calculate concentrations and temperatures without detailed knowledge of flow patterns and heat and mass transfer rates.
Although this example shows the applicability of the equilibrium stage method for equipment built with a series of discrete stages, we will see that the staged design method can also be used for packed columns where there are no discrete stages.
This method is a major simplification in the design and analysis of chemical engineering separations that is used in Chapters 2 to A second useful concept is that of a unit operation.
The idea here is that although the specific design may vary depending on what chemicals are being separated, the basic design principles for a given separation method are always the same.
For example, the basic principles of distillation are always the same whether we are separating ethanol from water, separating several hydrocarbons, or separating liquid metals.
Consequently, distillation is often called a unit operation, as are absorption, extraction, etc. A more general idea is that design methods for related unit operations are similar.
Since distillation and absorption are both liquid-vapor contacting systems, the design is much the same for both. This similarity is useful because it allows us to apply a very few design tools to a variety of separation methods.
We will use stage-by-stage methods where calculation is completed for one stage and then the results are used for calculation of the next stage to develop basic understanding.
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Just close this window! The physical characteristics that are often affected are the width, depth, longitudinal slope, bed elevation, and sediment load.
The Vermont Rivers Program wants to manage conflict between the dynamic nature of rivers and streams fluvial systems and human investments along stream corridors, avoid the exacerbation of existing and the creation of new conflicts, and support the reduction of existing conflict.
When humans interact near streams through construction or roadways, the stream tries to naturally adjust and re-establish its equilibrium.
Dependent on the amount of disturbance humans create, streams sometimes cannot reestablish equilibrium. When streams are knocked out of equilibrium they can take decades to reestablish and can be dramatically different than before.
There are some streams that are effected to such as extent that they can no longer reach equilibrium and the existing stream becomes extinct.
The most significant consequence of this is the loss of the resilience, energy attenuation capacity, and ecosystem services provided by fluvial systems.
Streams have natural adjustments that attempt to keep the equilibrium. Degradation, aggradation, widening, and plan-form change are some of the natural adjustments that streams make.
All of these natural occurrences work in balance to maintain equilibrium. An example of this can be seen when a river reaches its least erosive form, there is a balance of fluvial processes and we tend to see slow, natural meandering rivers.
When the river or stream is not in balance you will see increased flood damage. When a river changes plan form and forms a new channel, a change in the channel slope results.